Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Main active faults and seismic activity along the Yangtze River Economic Belt: Based on remote sensing geological survey     

《China Geology》2020,3(2):314-338

The Yangtze River Economic Belt (YREB) spans three terrain steps in China and features diverse topography that is characterized by significant differences in geological structure and present-day crustal deformation. Active faults and seismic activity are important geological factors for the planning and development of the YREB. In this paper, the spatial distribution and activity of 165 active faults that exist along the YREB have been compiled from previous findings, using both remote-sensing data and geological survey results. The crustal stability of seven particularly noteworthy typical active fault zones and their potential effects on the crustal stability of the urban agglomerations are analyzed. The main active fault zones in the western YREB, together with the neighboring regional active faults, make up an arc fault block region comprising primarily of Sichuan-Yunnan and a “Sichuan-Yunnan arc rotational-shear active tectonic system” strong deformation region that features rotation, shear and extensional deformation. The active faults in the central-eastern YREB, with seven NE-NNE and seven NW-NWW active faults (the “7-longitudinal, 7-horizontal” pattern), macroscopically make up a “chessboard tectonic system” medium-weak deformation region in the geomechanical tectonic system. They are also the main geological constraints for the crustal stability of the YREB.  相似文献   

Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中的生烃母质特征     

郑庆华  刘行军  刘乔  梁秀玲  张小龙  左琴  杨开艳  马婷  许锋 《岩矿测试》2020,39(3):442-450

鄂尔多斯盆地上三叠统延长组长7油层组的黑色泥岩、油页岩等黑色生油岩薄片中的生烃母质,因黑色石油、沥青等黑色有机质的覆盖或不透明,导致其在偏光显微镜透射光系统下观察常局部或整体呈现为黑色。因此,建立一种黑色生油岩薄片中生烃母质有效观察的方法,对致密油、页岩油的生烃研究具有重要的理论和实际意义。本文提出了一种利用电子探针薄片和偏光显微镜的反射光系统观察黑色生油岩中生烃母质特征的方法。该方法能够克服黑色生油岩薄片中生烃母质因被黑色有机质覆盖或不透明,而在偏光显微镜的透射光系统下局部或整体呈黑色的弊端,能够对生烃母质的大小、形态、结构、分布和物质成分等特征进行整体且清晰的观察。实践表明,本文提出的利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中生烃母质特征的方法,简单有效,易在致密油、页岩油的生烃研究领域推广使用。  相似文献   

基于F-范数的不确定性平差模型的解算方法     

鲁铁定  朱国红 《大地测量与地球动力学》2018,38(6):557-561

为提高基于F-范数的不确定性平差模型的解算效率，给出直接迭代算法进行参数估计。该算法无需SVD，解算过程简单且易于编程计算，同时给出迭代不收敛时的SVD-解方程算法。二元线性拟合及沉降观测AR模型的算例结果表明，这2种算法正确可行，与SVD-迭代算法具有等价性。当迭代收敛时，宜使用直接迭代算法，收敛速度更快，解算效率更高；当迭代不收敛时，可釆用SVD-解方程算法。  相似文献   

基于灯光数据的京津冀城市多标度异速分析     

龙玉清  陈彦光 《地理科学进展》2019,38(1):88-100

城镇体系的时空演化是一个复杂的动力学过程,具有无尺度性,其特征可以采用异速标度指数定量描述。论文以京津冀为例,基于1992—2013年夜间灯光数据的校正结果,提取城镇夜间灯光信息,采用多标度异速分析方法,分析京津冀城镇体系的相对发展特征及其空间分异格局。研究发现：①京津冀大城市的增长空间局限日益显著。虽然大城市如京津唐的绝对发展水平高,但接近环境承载量的极限,22 a间增长快速的是大城市交接地带的小城市(如三河、迁安、廊坊等)。②相对增长速度快的城市从东北到西南呈现带状分布——政府选择发展的“雄安新区”就在这个轴带上。由此可以得出两个结论：其一,京津冀城市演化的趋势相对均衡化,空间结构异质性逐步减弱,整个城镇体系的发展趋于相对平衡状态;其二,大、小城市“两极”贯通或许是增强城镇体系功能的有效途径。京津冀的空间格局优化不能仅仅考虑主要的、规模大的中心城市,而应该基于等级结构协调整个城镇网络体系。  相似文献   

Study of irregular wave run-up over fringing reefs based on a shock-capturing Boussinesq model     

《Applied Ocean Research》2019

This paper presents the results of a parametric study of irregular wave run-up over fringing reefs using the shock-capturing Boussinesq wave model Funwave-TVD to better understand the role of fringing reefs in the mitigation of wave-driven flooding. Laboratory experiments were newly performed with a typical fringing reef profile and typical hydrodynamic conditions to validate the model. Experimental data shows irregular wave run-ups are dominated by the low-frequency motions and confirms the run-up resonant phenomenon over the back-reef slope, which has been revealed in previous numerical studies. It is demonstrated that irregular wave evolution and run-up over fringing reefs are reasonably reproduced by the present model with a proper grid size. However, the infragravity run-up height and highest 2% run-up height over the back-reef slope are under-predicted due to the underestimation of the infragravity wave height over the reef flat. The validated model was then utilized to model irregular wave transformations and run-ups under different conditions. Through a series of numerical experiments, the effects of key hydrodynamic and reef geometry parameters, including the reef flat width, water depth over the reef flat, fore-reef slope angle and back-reef slope angle, on the irregular wave run-up were investigated. Variations of spectral components of irregular wave run-ups were examined to better understand the physical process underlying the effect of each parameter.  相似文献   

全球气候变化下南海诸岛保护优先区识别分析   总被引：3，自引：1，他引：2  

左秀玲  苏奋振  张宇  吴文周  吴迪 《地理学报》2020,75(3):647-661

全球变化下,珊瑚礁保护区是保护生物多样性、增强珊瑚礁对气候变暖抵抗力的有效方式,而维持珊瑚礁弹性是其核心内容。针对珊瑚礁最具有威胁性的热压力因子,基于南海1982—2009年卫星观测海表面温度（SST）数据和CMIP5加拿大地球系统模式CanESM2模型预估的2006—2100年南海SST数据构建热压力强度模型,从维持珊瑚礁弹性的角度识别IPCC RCP 4.5和RCP 8.5情景下南海诸岛保护优先区。结果表明：RCP 4.5和RCP 8.5情景下13%左右的南海诸岛珊瑚礁识别为保护优先区。根据热压力强度与珊瑚抵抗力及避难所关系,西沙群岛七连屿和晋卿岛近年观测与未来预估的热压力强度均比较低,在保障其服务功能的基础上建议实施完全保护;东沙群岛东沙环礁和中沙环礁排洪滩近年观测急性热压力强度较高但未来预估热压力强度较低,建议实施50%禁止利用保护;中沙群岛黄岩岛近年观测和未来预估的急性热压力强度均比较低,建议实施50%多用途保护。南沙群岛有14%左右的珊瑚礁识别为保护优先区,根据其热压力强度可实施30%~100%禁止利用保护或30%~50%多用途保护。RCP 4.5和RCP 8.5情景下的南海诸岛保护优先区及保护对策,可为维持珊瑚礁生态弹性及应对全球气候变化提供重要的参考价值。  相似文献   

Lidar-aided analysis of boreal forest backscatter at Ku band     

《International Journal of Applied Earth Observation and Geoinformation》2020

This paper analyzes the backscatter of the microwave signal in a boreal forest environment based on a Ku -band airborne Frequency-Modulated Continuous Waveform (FMCW) profiling radar—Tomoradar. We selected a half-managed boreal forest in the southern part of Finland for a field test. By decomposing the waveform collected by the Tomoradar, the vertical canopy structure was achieved. Based on the amplitude of the waveform, the Backscattered Energy Ratio of Canopy-to-Total (BERCT) was calculated. Meanwhile, the canopy fraction was derived from the corresponding point cloud recorded by a Velodyne VLP-16 LiDAR mounted on the same platform. Lidar-derived canopy fraction was obtained by counting the number of the first/ the strongest returns versus the total amount of returns. Qualitative and quantitative analysis of radar-derived BERCT on lidar-derived canopy fraction and canopy height are investigated. A fitted model is derived to describe the Ku-band microwave backscatter in the boreal forest to numerically analyze the proportion contributed by four factors: lidar-derived canopy fraction, radar-derived canopy height, the radar-derived distance between trees and radar sensor and other factors, from co-polarization Tomoradar measurements. The Root Mean Squared Error (RMSE) of the proposed model was 0.0958, and the coefficient of determination R2 was 0.912. The fitted model reveals that the correlation coefficient between radar-derived BERCT and lidar-derived canopy fraction is 0.84, which illustrates that lidar surface reflection explains the majority of the profiling /waveform radar response. Thus, vertical canopy structure derived from lidar can be used for the benefit of radar analysis.  相似文献   

300 BC-1900 AD无定河流域城镇时空格局演变   总被引：2，自引：1，他引：1  

佟彪  党安荣  许剑 《地理学报》2019,74(8):1508-1524

通过分析和整理从战国中晚期（约300 BC）至清末（约1900 AD）无定河流域历代县级及以上城址的位置、兴废年代数据,结合行政区划沿革、经济社会发展、政权更迭等资料,分析流域城镇格局的时空演变过程。研究表明：① 受气候周期性波动影响,无定河流域城镇的兴起与衰废具有明显的周期性特征,城镇几何中心的移动轨迹具有明显的“西北—东南”向潮汐性运动特征;② 城址存续年限普遍较短,具有明显的阶段性特征,流域内曾存在过4个阶段性中心城镇,中心城镇移动的方向和过程与城镇几何中心的潮汐性移动过程趋势一致;③ 流域城镇空间格局可分为3种类型,即秦汉与隋唐时期的沿河流谷地分布,宋、明两代的沿边境线与长城分布,以及元、清两代集中于流域下游分布。流域城镇未来的发展布局应重视气候变化对城镇分布的长期影响,关注区域环境的脆弱性,合理安排城镇体系发展规模与布局。  相似文献